Classification and identification of gas–liquid dispersion states in a jet bubbling reactor

Three gas–liquid dispersion states including flooding, loading, and complete dispersion are observed sequentially in a jet bubbling reactor with an increase of the liquid jet velocity at the nozzle outlet (u_j). The gas–liquid dispersion states are identified through the slope (k) of the curve of fluctuation distribution index (FI) versus u_j as follows: (a) under the flooding, k = 0; (b) under the loading, k > 0; (c) under the complete dispersion, k < 0. In particular, the u_j at the transition points from flooding to loading and from loading to complete dispersion are referred to flooding jet velocity (u_jf, the transition point between k = 0 and k > 0) and complete dispersion jet velocity (u_jcd, the transition point from k > 0 to k < 0), respectively. The average relative deviations of the u_j at the transition points obtained through the acoustic emission measurement and visual observation are less than 5%.     

Preparation of tunable full-color emission carbon dots and their optical applications in ions detection and bio-imaging

In this work, we synthesized a series of novel carbon dots (CDs) by using phenylenediamines (three isomers: o-phenylenediamine, m-phenylenediamine, and p-phenylenediamine) as starting materials via facile solvothermal approach. As-prepared CDs could emit bright blue, green, yellow, orange, and red light with relatively high PLQY, individually. Optical properties could be controlled by simply varying reaction parameters. The luminescent mechanism was investigated and analyzed in detail. Finally, the blue-emitting CDs and green-emitting CDs showed many appealing properties, such as high sensitivity (limit of detection = 4.52 and 3.50 nmol/L), quick response (<2 minutes), broad response window (0-70 nmol/L), and excellent selectivity for detecting Cr⁶⁺ and Al³⁺ cations, respectively. Thus, they have potential to be developed as the corresponding optical probes. While as-prepared orange-emitting CDs could be applied as a bio-imaging reagent due to its long-wavelength emission, relatively high PLQY, low toxicity, excellent water solubility, and good biocompatibility.     

基于AIC信息准则的Delta T声发射源定位方法

疲劳断裂是金属结构中的主要失效形式,而金属结构中的早期疲劳断裂信号通常难以检测。TOA方法是常用的声发射定位源方法,但是声波传播过程中波速变换和路径的复杂性对其结果影响很大。运用Delta T声发射源定位方法,用断铅实验模拟声发射源,用AIC信息准则对到达时间进行优化,通过使用差值求源点坐标和图像处理的方法,求得声发射源坐标。通过在平板上的实验,比较两种源定位方法在不同结构中的定位结果,分析定位误差,结果表明图像处理方法更为优秀。     

双碳目标下的钢铁节能理念创新与能源结构重塑探讨

在“碳达峰”“碳中和”背景下,中国钢铁必须走脱碳化发展道路,提高能效是当前最为行之有效的举措之一。通过分析钢铁行业存在的较大节能潜力及拥有丰富二次能源的用能特点,在热力学定律、系统最小外部损失、最佳推动力、能源梯级利用等几项基本原则的基础上,提出钢铁行业多能互补与储能相结合的创新理念,包括钢铁二次能源与可再生能源的互补、钢铁不同高低品位能源的互补、储能系统的创新应用等。从中长期看,需以更高的站位,走能源资源环境、高效清洁低碳一体化协同创新道路,构建化工-能源-生态一体化用能系统,进行合理优化与集成,实现能效提升及协同碳减排。     

电子调速器控制器的电磁兼容分析与试验验证

基于辐射发射的形成机理,以某型号电子调速器控制器为目标,利用EMSCAN电磁干扰扫描系统对控制器进行近场辐射测试,总结出一套切实可行的辐射发射分析与试验验证方法.在此基础上,对该型号电子调速器控制器进行了整改设计,并进行了试验验证.结果 表明:基于EM-SCAN系统的分析及整改方法效果明显,缩短了电子产品电磁兼容问题的整改设计周期,并节约了测试成本.     

The effect of Li+ incorporation in Yb3+-Nd3+ co-doped CaF2 phosphors over the NIR photoluminescence emission excited under visible light

The structural and optical characteristics of Nd³⁺-Yb³⁺ doped CaF₂ phosphors with and without the addition of Li⁺ ions are described in this work. The phosphors synthetized by hydrothermal and co-precipitation methods showed near-infrared (NIR) luminescence emission associated with inter-electronic transition of the Yb³⁺ ion in the range of 900–1050 nm via energy transfer process from Nd³⁺ ions under visible light excitation. The addition of Li⁺ to these phosphors resulted in an improvement of the NIR luminescence intensity by a factor up to 5. The effect of the incorporation of Li⁺ ions into the CaF₂ crystallite structure, the reduction of luminescence quenching states, as well as the energy transfer mechanism involved are discussed.     

Compact Quantum-Dot Microbeads with Sub-Nanometer Emission Linewidth

Fluorescent microbeads are widely used for applications in life sciences and medical diagnosis. The spectral contrast and sharpness of photoluminescence are critical in the utilities of microbeads for imaging and multiplexing. Here, microbeads capable of generating single-peak laser emission with a sub-nanometer linewidth are demonstrated. The microbeads are made of quantum dots that are tightly packed and crosslinked via ligand exchange for high optical gain and refractive index as well as material stability. Bright single-mode lasing with no photobleaching is achieved with particle diameters as small as 1.5 µm in the air. Sub-nm lasing emission is maintained even inside high-index surroundings, such as organic solvents and biological tissues. Feasibility of intracellular tagging and multi-color imaging in vivo is demonstrated.     

Influences of hydrogen and various gas fuel addition to different liquid fuels on the performance characteristics of a spark ignition engine

This study reports the impacts of dual fuel mixtures on the theoretical performance characteristics of a spark ignition engine (SIE). The effects of addition of liquefied hydrogen, methane, butane, propane (additive fuels) into gasoline, iso-octane, benzene, toluene, hexane, ethanol and methanol fuels (primary fuels) on the variation of power, indicated mean effective pressure (IMEP), thermal efficiency, exergy efficiency, were examined by using a combustion model. The fuel additives were ranged from 10 to 50% by mass. The results exhibited that the ratios of hydrogen, methane, butane, propane noticeably affect the performance of the engine. The maximum increase ratio of power is 82.59% with 50% of toluene ratio and its maximum decrease ratio is 10.84% with 50% of methanol ratio in hydrogen mixtures. The maximum increase ratio of thermal efficiency and exergy efficiency are observed as 26.75% and 32.23% with the combustion of benzene-hydrogen mixtures. The maximum decrease ratio of thermal efficiency is 29.71% with the combustion of 50% of methanol ratio and it is 21.95% for the exergy efficieny with the combustion of 50% of ethanol ratio in hydrogen mixtures. The power, IMEP, thermal efficiency and exergy efficiency of primary fuels demonstrate different variation characteristics with respect to type and ratio of additive fuels.     

Multi-objective planning and optimization of microgrid lithium iron phosphate battery energy storage system consider power supply status and CCER transactions

Lithium iron phosphate battery (LIPB) is the key equipment of battery energy storage system (BESS), which plays a major role in promoting the economic and stable operation of microgrid. Based on the advancement of LIPB technology and efficient consumption of renewable energy, two power supply planning strategies and the china certified emission reduction (CCER) model are proposed respectively. Based on it, the multi-objective planning optimization model with economic benefits, environmental benefits and power supply stability as the objective function is established for the first time, and the Newton Weighted Sum Frisch method (NWSFA) solution model is adopted. In the planning process, rain flow counting method is used to research the life of BESS, which improves the accuracy of energy storage annual cost calculation. A park in northern China is taken as a case study to demonstrate the application of this model. The simulation results show that the annual economic operating cost of BESS is decreased by 18.81%, the energy supply reliability is increased by 0.15%, and the optimal electricity price adjustment ratio of the system is 15%.     

Co-firing hydrogen and dimethyl ether in a gas turbine model combustor: Influence of hydrogen content and comparison with methane

To promote the utilization of hydrogen (H₂) in existing gas turbines, dimethyl ether (DME) was used to co-fire with H₂ in a model combustor. The swirl combustion characteristics of DME/H₂ mixtures were measured under the varying H₂ content up to 0.7. The results show that the flow velocity elevates as the H₂ content increases, which is associated with the increased flame temperature. The OH level firstly increases and subsequently keeps nearly unchanged as the H₂ content increases. Meanwhile, the OH area nonlinearly increases with the increasing H₂ content. Moreover, the increasing H₂ content induces almost linearly decreased lean blowout limit (LBO), increased NO emission, and intensified combustion acoustics. Furthermore, the combustion characteristics of the 0.46DME/0.54H₂ mixture and CH₄ with the same volumetric heat value were compared. The 0.46DME/0.54H₂ flame displays lower LBO and higher NO emission than the CH₄ flame, which mainly results from the higher reactivity of 0.46DME/0.54H₂ mixture.